In physics and chemistry, plasma is a partially ionized gas, in which a certain proportion of electrons are free rather than being bound to an atom or molecule. The ability of the positive and negative charges to move somewhat independently makes the plasma electrically conductive so that it responds strongly to electromagnetic fields. Plasma therefore has properties quite unlike those of solids, liquids or gases and is considered to be a distinct state of matter. Plasma typically takes the form of neutral gas-like clouds, as seen, for example, in the case of stars. Like gas, plasma does not have a definite shape or a definite volume unless enclosed in a container, but, unlike gas, in the influence of a magnetic field, it may form structures such as filaments, beams and double layers (see section 3, below).
Plasmas are by far the most common phase of matter in the universe, both by mass and by volume. All the stars are made of plasma, and even the space between the stars is filled with a plasma, albeit a very sparse one (See astrophysical plasma, interstellar medium and intergalactic space). In our solar system, the planet Jupiter accounts for most of the non-plasma, only about 0.1% of the mass and 10−15% of the volume within the orbit of Pluto. Very small grains within a gaseous plasma will also pick up a net negative charge, so that they in turn may act like a very heavy negative ion component of the plasma (see dusty plasmas).
Plasma temperature is commonly measured in kelvins or electronvolts, and is an informal measure of the thermal kinetic energy per particle. In most cases the electrons are close enough to thermal equilibrium that their temperature is relatively well-defined, even when there is a significant deviation from a Maxwellian energy distribution function, for example due to UV radiation, energetic particles, or strong electric fields. Because of the large difference in mass, the electrons come to thermodynamic equilibrium amongst themselves much faster than they come into equilibrium with the ions or neutral atoms. For this reason the "ion temperature" may be very different from (usually lower than) the "electron temperature". This is especially common in weakly ionized technological plasmas, where the ions are often near the ambient temperature. Based on the relative temperatures of the electrons, ions and neutrals, plasmas are classified as "thermal" or "non-thermal". Thermal plasmas have electrons and the heavy particles at the same temperature i.e. they are in thermal equilibrium with each other. Non-thermal plasmas on the other hand have the ions and neutrals at a much lower temperature (normally room temperature) whereas electrons are much "hotter".
Temperature controls the degree of plasma ionization. In particular, plasma ionization is determined by the "electron temperature" relative to the ionization energy (and more weakly by the density) in a relationship called the Saha equation. A plasma is sometimes referred to as being "hot" if it is nearly fully ionized, or "cold" if only a small fraction (for example 1%) of the gas molecules are ionized (but other definitions of the terms "hot plasma" and "cold plasma" are common). Even in a "cold" plasma the electron temperature is still typically several thousand degrees Celsius. Plasmas utilized in "plasma technology" ("technological plasmas") are usually cold in this sense.
Sunday, May 31, 2009
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